Semi-circular sweep voltammetry. Bio-analytical applications
نویسندگان
چکیده
A novel voltammetric method applying a semi-circular potential sweep is applied to the simultaneous electroanalytical determination of solutions containing two components with similar oxidation potentials which precludes their resolution using conventional methods including linear sweep, square wave and pulse voltammetries. Three such biologically important mixtures, ascorbic acid/acetaminophen, glucose/ethanol hydroquinone/catechol were studied, analytical developed voltammetry shown give notable advantages over other voltammetries in terms signal sensitivity detection. Favourable accuracy was obtained electrodes either simple or no modification established detection ranges.
منابع مشابه
Determination of Mexiletine in Pharmaceutical Preparations by Linear Sweep Voltammetry
A simple and rapid method for determination of mexiletine in pharmaceutical preparations was developed and validated using linear sweep voltammetry (LSV). The proposed method was based on electrochemical oxidation of mexiletine at platinum electrode in acetonitrile solution containing 0.1 M LiCIO4. The well-defined an oxidation peak was observed at +1.11 V. The calibration curve was linear for ...
متن کاملAn Analytical and Semi-analytical Study of the Oscillating Flow of Generalized Burgers’ Fluid through a Circular Porous Medium
Unsteady oscillatory flow of generalized Burgers’ fluid in a circular channel tube in the porous medium is investigated under the influence of time-dependent trapezoidal pressure gradient given by an infinite Fourier series. An exact analytical expression for the solution for the fluid velocity and the shear stress are recovered by using the similarity arguments together with the integral trans...
متن کاملEvaluation of Two Semi-analytical Techniques in Air Quality Applications
In this article an evaluation of two semi-analytical techniques is carried out, considering the quality and accuracy of these techniques in reproducing the ground-level concentration values of passive pollutant of the advection-diffusion equation by the Laplace transform technique. The second is a Lagrangian model based on solution of the Langevin equation through the Picard Iterative Method. T...
متن کاملDetermination of Bosentan in Pharmaceutical Preparations by Linear Sweep, Square Wave and Differential Pulse Voltammetry Methods
In this study, simple, fast and reliable cyclic voltammetry (CV), linear sweep voltammetry (LSV), square wave voltammetry (SWV) and differential pulse voltammetry (DPV) methods were developed and validated for determination of bosentan in pharmaceutical preparations. The proposed methods were based on electrochemical oxidation of bosentan at platinum electrode in acetonitrile solution containin...
متن کاملDetermination of Bosentan in Pharmaceutical Preparations by Linear Sweep, Square Wave and Differential Pulse Voltammetry Methods
In this study, simple, fast and reliable cyclic voltammetry (CV), linear sweep voltammetry (LSV), square wave voltammetry (SWV) and differential pulse voltammetry (DPV) methods were developed and validated for determination of bosentan in pharmaceutical preparations. The proposed methods were based on electrochemical oxidation of bosentan at platinum electrode in acetonitrile solution containin...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Biosensors and Bioelectronics
سال: 2021
ISSN: ['0956-5663', '1873-4235']
DOI: https://doi.org/10.1016/j.bios.2021.113083